Two ophiolitic mélange belts, the South Central Tianshan Ophiolite Belt (SCTOB) and the South Tianshan Ophiolite Belt (STOB), extend almost parallel to the Chinese South Tianshan Orogen — the southernmost part of the Central Asian Orogenic Belt (CAOB). The SCTOB occurs interlayered in the South Central Tianshan Suture Zone, the STOB as exotic blocks in Palaeozoic sedimentary strata. However, their tectonic settings and ages, which are crucial for understanding the formation of the CAOB, are still controversially discussed. In order to better understand these geological problems, geological, geochemical and geochronological investigations were conducted on the Guluogou (SCTOB) as well as on the Serikeyayilake and Aertengkesi ophiolitic mélanges (STOB). The ophiolitic suites are composed of basalts, gabbros and mantle peridotites. Laser ablation ICP-MS (LA-ICP-MS) U–Pb zircon ages of 334±5Ma and 332±7Ma were obtained for the Guluogou gabbros, while SHRIMP U–Pb zircon ages of 423±10Ma and 423±4Ma were determined for the Serikeyayilake and Aertengkesi gabbros. The mineral composition of the mantle peridotites and the geochemical characteristics of the basalts suggest a mid-ocean ridge (MOR) type affinity for the Guluogou ophiolite and a SSZ type affinity for the Serikeyayilake and Aertengkesi ophiolites. The present data, combined with previously published results, indicate that the STOB may have been derived from a forearc rifting setting that existed during the early Silurian to the early Carboniferous (ca. 439–356Ma), whereas the SCTOB may represent fragments of a normal wide ocean that lasted to the early Carboniferous (ca. 332Ma).