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A systematic study, based on density functional theory and different hybrid functionals for exchange-correlation potential, shows that the electron affinities of organo-zintl clusters [Ge9(R)n] [R=CHO; n=1, 3] are close to that of chlorine (3.6eV) and iodine (3.0eV). A detailed study of the molecular orbitals of these complexes, when compared to those of Al13−, Cl− and I−, confirm that they behave...
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