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The binary phase diagrams of the NdCl 3 –MCl (M=Li, Na, K, Rb, Cs) systems were studied using the CALPHAD technique. For describing the Gibbs energies of the liquid phase in these systems, the new modified quasi-chemical model in the pair-approximation for short-range ordering was used. Based on measured phase equilibrium data and experimental thermochemical properties, a set of thermodynamic...
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