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The phase equilibria of the binary Gd–Ti system were studied by combining electrostatic levitation of the melt with high energy synchrotron in situ X-ray diffraction at elevated temperatures. The coexistence of the phases including the liquid was directly proven in the temperature range between T=1000 and 1920K. The Gd–Ti system is of monotectic type characterized by a miscibility gap in the liquid...
The Cd–X (X= Sr, Ti, B, V) systems have been critically reviewed and modeled by means of the CALPHAD approach. The eight compounds, SrCd11, SrCd6, Sr13Cd58, SrCd2, SrCd, Sr5Cd3, TiCd and Ti2Cd, were treated as stoichiometric phases. By means of first-principles calculations, the enthalpies of formation at 0K for the SrCd11, SrCd2, SrCd and Sr5Cd3 have been computed to be −13892.5, −33985.2, −32280...
The Ni–Sc system was thermodynamically assessed by the CALPHAD approach based on the available experimental data including the thermodynamic properties and phase equilibria. The excess term of the Gibbs energy of the solution phases (liquid, b.c.c., f.c.c. and h.c.p.) was assessed with the recent exponential temperature dependence of the interaction energies by Kaptay (Calphad 28–2 (2004) 115–124;...
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