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The interaction of CO with differently modified polycrystalline ZnO has been studied by FTIR spectroscopy under ultrahigh vacuum conditions (UHV-FTIRS). After exposing the clean, adsorbate-free ZnO nanoparticles to CO at 110K we observe an intense vibrational band at 2187cm −1 which is assigned to a majority of CO species bound to the Zn 2+ sites on the mixed-terminated ZnO(1 0 1¯...
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