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The reactivity and stability of the carbonate species formed at the surface of a Pt/CeO 2 catalyst during the reverse was-gas-shift (RWGS) reaction was investigated by in situ diffuse reflectance (DRIFT) FT-IR spectroscopy at 523K. Like most oxide materials presenting some basic character, the surface of the sample (not yet exposed to the RWGS stream) exhibited a significant concentration...
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