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Contribution of step-in geometric discontinuity to the longitudinal coupling impedance has been obtained analytically using exact field matching. We assumed a perfectly conducting beam-pipe wall of two different radii connected coaxially at z=0 so that the contribution to the longitudinal coupling impedance is purely due to the beam-pipe geometric discontinuity. We also obtained the longitudinal loss factor for a Gaussian beam as a function of beam energy and bunch length. Results have been analyzed numerically for some representative parameters close to real machine parameters. Analytical results have also been compared with numerical simulation from CST at relativistic beam energies. We found a very good agreement between theory and simulation.