Li-ion batteries made from LiFePO 4 cathode and anatase TiO 2 /graphene composite anode were investigated for potential application in stationary energy storage. Fine-structured LiFePO 4 was synthesized by a novel molten surfactant approach whereas anatase TiO 2 /graphene nanocomposite was prepared via self-assembly method. The full cell that operated at 1.6V demonstrated negligible fade even after more than 700 cycles at measured 1C rate. While with relative lower energy density than traditional Li-ion chemistries interested for vehicle applications, the Li-ion batteries based on LiFePO 4 /TiO 2 combination potentially offers long life and low cost, along with safety, all which are critical to the stationary applications.