The precipitation behaviors of Zr–rich phase in binary Al–0.5Zr and ternary Al–3Si–0.5Zr alloys were investigated by high resolution transmission electron microscopy and atom probe. After the alloys were aged at 525 °C for 24 h, the precipitates in Al–0.5Zr alloy are identified as L12–ZrAl3, performing a coherent relationship with the Al matrix. While in Al–3Si–0.5Zr alloy, the precipitates are Si–containing D023–Zr(Al,Si)3, which has an approximate 90° reversed cube–on–cube orientation relationship with Al. It is regarded that Si accelerates the precipitation of D023–Zr(Al,Si)3.