Arnold tongue structures generated due to the mutual entrainment of two periodic oscillators are studied experimentally and numerically. This mutual entrainment is provoked due to the mutual (bidirectional) coupling between the two oscillators. In experiments, this bidirectional coupling is achieved by immersing a pair of anodes (oscillators) in a common electrolytic solution. A voltage mismatch between these anodes renders the time period of the uncoupled oscillators non-identical. Moreover, the coupling strength between the two oscillators is uniquely determined by the Euclidean distance separating them. Systematically varying the distance between these two anodes as a function of their voltage mismatch, phase locked domains were located. Subsequently, Arnold tongue structures were constructed in the experiments. Numerical simulations, using a model for electrochemical corrosion, corroborate our experimental findings.