We report an in situ STM study of a potential-dependent long-range surface restructuring of Au(111) electrode in neat 1-butyl-3-methylimidazolium tetrafluoroborates (BMIBF 4 ) ionic liquid. Au(111) undergoes a significant long-range surface restructuring upon cathodic excursion to -1.0 V vs. Pt quasi-reference. The restructuring involves the formation of tiny pits, which then develops into a stable worm-like network with an average width of the network grids ~2 nm. Electrochemical annealing occurs at the cathodic limit with the presence of a reduction product of cation BMI + . A smooth surface is recovered with the appearance of the typical (√3x22) reconstruction of Au(111). The surface restructuring is reestablished upon anodic excursion to -1.3 V after the adsorbed reduction product is oxidized. The long-range surface restructuring phenomenon is tentatively explained as a result of partial charge transfer to the weakly adsorbed BMI + , which reduces the metal-metal cohesive energy. In addition, the synergetic effect of the counter anion BF 4 - may also be involved. The results provide a knowledge of Au(111) electrode behavior in the neat ionic liquid and are beneficial to understanding in situ STM results involving surface morphological changes in such a media.