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Novel copper(II) and cobalt(II) complexes of the N-hydroxyethyl-N-benzimidazolylmethylethylenediaminediacetic acid were prepared and their X-ray crystal structures were determined. Both complexes are hexacoordinate and exhibit a distorted octahedral geometry. The urease inhibitory activity of the complexes was measured (alongside with the free ligand and acetohydroxamic acid as reference substance)...
In the present study, the coordination abilities of Ac-TLEGTKKGHKLHLβDY-NH2 peptide (the analogue of SPARC 114–128 fragment containing β-Asp127 residue) are discussed. The analysis is provided based on the results of potentiometric and spectroscopic measurements supported by quantum-chemical calculations. Presented results clearly show that the β-Asp amino acid residue may influence the efficiency...
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