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We report the selective association of a novel bipolarofacial, bowl-shaped molecule (I) with Fe 3+ and PdCl42- ions. UV–vis titration experiments and Langmuir isotherm measurements revealed stronger association with the palladate over the iron ions, both in homogeneous organic medium as well as at the air–water interface. Interestingly, we found that the complexation is solvent-dependent,...
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