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New P,N-bidentate aminophosphite ligands OCH 2 CH 2 N(R)PO(CH 2 ) n NMe 2 (2a R=Me, n=2; 2b R=t-Bu, n=2; 3 R=t-Bu, n=3) have been obtained and characterized. Complexation of all the ligands with [PdCl 2 (COD)] (COD=1,5-cyclooctadiene) has been investigated. Ligands 2a,b have been found to form mononuclear chelate complexes [PdCl 2 (PN)]. Ligand...
A series of amino phosphites having phosphorus or/and nitrogen atoms, which are included in a six-membered cycle, has been synthesized. The presence of such cycles in these P,N-bidentate ligands has been shown to strongly influence the ways of their coordination with Rh(I) and Pd(II) atoms. The resulting chelate complexes have been found to be less stable when the six-membered chelate metalacycle...
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