Dicyclohexyl telluride, Te(cyclo-C 6 H 1 1 ) 2 , a somehow surprisingly not reported molecule, is synthesized and characterized by multinuclear NMR, IR and Raman spectroscopy. A temperature dependence of the NMR spectra ( 1 2 5 Te{ 1 H}, 1 3 C{ 1 H}) for Te(cyclo-C 6 H 1 1 ) 2 is observed and studied in detail. The 1 2 5 Te-NMR spectrum of Te(cyclo-C 6 H 1 1 ) 2 at different temperatures is calculated and compared with the experimental spectra. The vibrational spectra of Te(cyclo-C 6 H 1 1 ) 2 and values calculated ab initio at HF/3-21G* level are discussed. The Raman spectra of symmetric dialkyl tellurides TeR 2 with R 2 =(n-C 3 H 7 ) 2 , (i-C 3 H 7 ) 2 , (n-C 4 H 9 ) 2 and (n-C 6 H 1 3 ) 2 are reported and TeC stretching frequencies assigned. In addition, thorough NMR characterization of those derivatives ( 1 2 5 Te{ 1 H}, 1 3 C{ 1 H}, 1 H) is given.