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In this paper, the liquid–liquid equilibrium of thirty ternary systems relevant for biodiesel production was modeled using the NRTL and UNIQUAC equations and the Backtracking Search Optimization algorithm (BSOA). Performance of this new optimization method for liquid–liquid equilibrium (LLE) parameter estimation, with and without the application of the closure equations, has been analyzed and compared...
Liquid–liquid equilibrium (LLE) data are reported for the ternary mixtures of (acetonitrile+a carboxylic acid+dodecane) at 303.15K under atmospheric pressure, where a carboxylic acid refers to acetic acid, propanoic acid, butanoic acid, 2-methylpropanoic acid, pentanoic acid and 3-methylbutanoic acid. The area of the two-phase heterogeneous region for the carboxylic acid mixtures decreases in the...
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