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An all-glass, dynamic recirculating still equipped with an ultrasonic homogenizer has been used in the determination of the vapour–liquid equilibrium (VLE) and vapour–liquid–liquid equilibrium (VLLE). Consistent data for the ternary water+ethanol+toluene system are reported at 101.3kPa at temperatures in the range of 347–357K. These data have been compared with previously published VLLE data. The...
A correlation method for isobaric vapor–liquid equilibria (VLE) and vapor–liquid–liquid equilibria (VLLE) of binary systems was proposed. Taking the coordination number in UNIQUAC model as a fitting parameter (three-parameter UNIQUAC model) and employing an objective function of relative difference between the experimental and the predicted temperatures of VLE data, the experimental VLLE data were...
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