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A perturbed hard-sphere-chain (PHSC) equation of state is developed for normal fluids and polymers, including mixtures. The new PHSC equation of state for pure fluids uses a perturbation term based on the analytic solution by Chang and Sandler to the second-order perturbation theory of Barker and Henderson for the square-well fluid of variable width. The reference equation of state is the modified...
The orthobaric liquid-liquid phase diagrams for the five binary mixtures of propanenitrile with the n-alkanes C 5 -C 8 and C 10 have been determined by visual observation of the separation temperatures of mixtures of known mass composition. The results have been fitted to a conventional modern expression incorporating where needed Wegner extended-scaling terms. Various...
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