In and Ta co-doping BaCeO 3−δ (BaCe 0.7 Ta 0.1 In 0.2 O 3−δ ) powders were synthesized by an improved route combining solid state reaction and wet chemical method. Green BaCe 0.7 Ta 0.1 In 0.2 O 3−δ (BCTI) |NiO+BaCe 0.7 Zr 0.1 Y 0.2 O 3−δ (BZCY) half cells were successfully fabricated by co-pressing BCTI powders on NiO–BZCY substrate, which were sintered at a relatively low temperature of 1300°C for 5h and then produced dense BCTI membrane. The stability testing showed that BCTI membrane is excellently stable against carbon dioxide and boiling water. A single fuel cell with 44μm-thick BCTI electrolyte was assembled by brushing Sm 0.5 Sr 0.5 CoO 3−δ Ce 0.8 Sm 0.2 O 2−δ (SSC–SDC) composite cathode on dense electrolyte membrane, which generated maximum power densities of 59, 49, 34mW/cm 2 at 650, 600 and 550°C, respectively. Meanwhile, the resistances of the cell were measured by electrochemical impedance spectroscopy under open circuit condition. Moreover, the long-term test of the cell showed stable power output and open circuit voltages. The above described performance indicates that BCTI is stable electrolyte material for intermediate-temperature solid oxide fuel cells. Besides, the super stable electrolyte material can be used as online high-temperature hydrogen sensor.