The nth-order solutions of the classical massive Thirring model (MTM) equations are derived by using the n-fold Darboux transformation. These solutions are expressed by the ratios of the two determinants consisted of 2n eigenfunctions under the reduction conditions. Using this method, rogue waves are constructed explicitly up to the third-order. Three patterns, i.e., fundamental, triangular and circular patterns, of the rogue waves are discussed. The parameter μ in the MTM model plays the role of the mass in the relativistic field theory while in optics it is related to the medium periodic constant, which also results in a significant rotation and a remarkable lengthening of the first-order rogue wave. These results provide new opportunities to observe rouge waves by using a combination of electromagnetically induced transparency and the Bragg scattering four-wave mixing because of large amplitudes.