Electrochemical measurements and friction measurements during continuous and intermittent unidirectional sliding tests are used to monitor and to evaluate the surface characteristics of two types of metallic materials characterized by a huge unit cell, namely Al 71 Cu 10 Fe 9 Cr 10 and Al 3 Mg 2 . The modification of the surface characteristics results from the periodic mechanical removal of a surface film during sliding, and the subsequent (electro)chemical re-growth of a surface film in-between successive sliding contacts. Al 71 Cu 10 Fe 9 Cr 10 and Al 3 Mg 2 materials were tested in a phosphate buffer solution pH 7 at 25°C to compare their depassivation and subsequent repassivation behaviour. The Al 3 Mg 2 material was also tested in a 0.1M KOH solution pH 13 and 25°C to reveal the role of constituting metallic elements on the surface film formation. The effect of film formation and removal on the coefficient of friction recorded during unidirectional sliding is discussed.