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This paper describes the preparations and lithium-ion conductivities of various solid polymer electrolytes for potential use in high-energy density lithium-ion batteries. The ring opening polymerization of epoxides (M1–M6), catalyzed by Zn(II), Cu(II) and Cd(II) complexes in the presence of tetrabutylammonium bromide (TBAB), yielded polyethers (P1–P6) in which phosphates were attached as pendant groups...
Polymerization of vinyl acetate (VAc) was carried out with four different cyclometalated ruthenium(II) catalysts, using CCl 4 as initiator under conventional heating and microwave irradiation. The thermo-polymerizations were solvent-dependent and proceeded to limited conversions without control. Only the polymerization in DMSO mediated by [Ru(η 6 -C 6 H 6 )(C 6...
A series of rare earth triflates (RE(OTf) 3 , RE = Sc, Y and Lu) were used for the first time as moisture-stable precursors to generate rare earth alkoxide complexes through an in situ reaction with sodium alkoxides (NaOR) in tetrahydrofuran. 1 H NMR and 13 C NMR results confirmed the fast ligands exchange process and the formation of rare earth–oxygen (RE–OR) bond. The in...
Copoly(ionic liquid)s (coPILs) based on poly(styrene)-co-poly(4-vinylbenzylbutylimidazolium) with different anions (Cl− and HCO3−), denoted as PS-co-PVBnBuImCl 1 and PS-co-PVBnBuImHCO3 2, were used as reactive polymers for the purpose of post-polymerization modification and organic catalysis. While coPIL 1 could be derived into the corresponding poly(N-heterocyclic carbene)-silver transition metal...
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