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The reaction of azo dye complexes ctc-[Ru(α/β-NaiR′) 2 Cl 2 ] (1) [α/β-NaiR′=1-alkyl-2-α/β-(naphthylazo)imidazole, C 10 H 7 –NN–C 3 H 2 NN(1)–R′, R′=Me (2), Et (3), Bz (4)] with (NH 4 ) 2 MoS 4 in aqueous MeOH afforded reddish violet colour mixed ligand complexes of the type [(α/β-NaiR′) 2 Ru(μ-S) 2 Mo(OH) ...
Large cadmium chalcogenido clusters C2 (Cd 32 ) and C1 (Cd 17 ) CdQ (Q = S, Se) with photoactive dye cations [Ru(Phen/Bpy) 3 ] 2+ are prepared under solvothermal conditions (Phen = 1,10-phenanthroline, Bpy = 2,2′-bipyridine). All the C2 compounds are 3-D polymeric structures, while the C1 compounds are discrete Cd17 clusters. Two of the 3-D C2 clusters can be considered...
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