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The unusual synthesis of the dimeric dithiolene complex [(PPh 3 )Pd(ethylene-1,2-dithiolate)] 2 (1), containing the simplest dithiolene ligand, has been achieved through the reaction between tetrathiafulvalene (TTF) and Pd(PPh 3 ) 4 . The complex shows a folded structure in the solid state, according to single crystal X-ray analysis performed on crystals grown from...
The paramagnetic dithiolene complex [Cu(mnt) 2 ] 2– (mnt: 1,2-dicyanoethylene-1,2-dithiolate) is used as metalloligand for coordination of dicationic [Cu(en) 2 ] 2+ (en: ethylenediamine) complex, leading to the formation of chains of alternating [Cu(mnt) 2 ] 2– and [Cu(en) 2 ] 2+ moieties through C≡N•••Cu•••N≡C trans coordination with...
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