Dense Y-α and duplex Y-α/β-sialon ceramics were fabricated by hot isostatic pressing (HIP) using the compositions with the formula Y m / 3 Si 1 2 - ( m + n ) Al m + n O n N 1 6 - n and extra addition of 2 wt.%Y 2 O 3 . The sintered materials were subsequently heat-treated at 1300-1700 o C to investigate the thermal stability of Y-sialons. The results show that α-sialon stabilized by yttrium has high thermal stability. An adjustment of α-sialon phase composition is the dominating reaction during annealing. Post heat-treatment has a little effect on the microstructure and properties of the Y-α/β-sialons, but significantly changes the morphology of α-phase grains in Y-α-sialons from elongated to equiaxed after heat-treatment at 1500 o C for extended time, hence decreasing its toughness.