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Complex study of the electronic structure of the Ag2HgSnSe4 compound employing both experimental and theoretical methods was carried out in the present work. In particular, X-ray photoelectron core-level and valence-band spectra for pristine and Ar+ ion-irradiated surfaces of Ag2HgSnSe4 single crystal have been measured. The present X-ray photoelectron spectroscopy (XPS) results indicate that Ag2HgSnSe...
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