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We have synthesized indium complexes containing a variety of metal bonding environments through use of polyfunctional dithiolate ligands and examined their reactivity as initiators for the ring-opening polymerization of l-lactide, rac-lactide, ε-caprolactone and β-butyrolactone. The facile reaction of Me3In with the corresponding polyfunctional dithiols in toluene, thf or diethyl ether resulted in...
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