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The reaction of multidentate azine Schiff-base ligands was investigated towards p-cymene ruthenium, Cp*Rh and Cp*Ir complexes. The reaction of [(arene)MCl2]2 (arene = p-cymene, Cp*; M = Ru, Rh and Ir) with azine Schiff-base ligands (L1-L3) in 1:2 M ratio led to the formation of mononuclear complexes of the type [(arene)M(L)Cl]+ whereas the reaction of [Cp*MCl2]2 (M = Rh/Ir) with azine Schiff-base...
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