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Cerium(III) chloride activated (+)-camphor (1) and (-)-fenchone (2) react with lithiated ferrocene (reagent 3, (Li-Cp) 2 Fe/LiCp-FeCp = 50:1) to give the corresponding optically active ferrocenyl diols 4 and 6 and monosubstituted ferrocenyl alcohols 5 and 7. The preparation of the diols 4 and 6, as well as of the alcohols 5 and 7 respectively, in high yields is optimized depending on the...
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