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Several new diorganobismuth(III) compounds based on a butterfly-like tetrahydro-dibenzo[c,f][1,5] thiabismocine heterocyclic framework were prepared and structurally characterized. The reaction between the dilithio derivative of bis(2-bromobenzyl)sulfane with BiBr3 in a 1:1 M ratio resulted in the formation of [(C6H4CH2)2S]BiBr (1). Further exchange reactions of 1 with KI, AgNO3 and AgOSO2CF3, respectively,...
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