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A series of complexes, [Pd(η 3 -C 3 H 5 )(P^PS)][SbF 6 ], where P^PS are bidentate bisphosphine monosulfide ligands, were found to catalyze allylic alkylation reactions with high branched:linear selectivity with some ligands. Some of these catalysts also display a regiochemical memory effect, in which the hemilability and rigidity of the P^PS ligands affect the reaction...
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