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The synthesis of alicyclic 3-iminophosphine ligands is extended to include a new framework incorporating a cyclohexenyl backbone with an N-aryl imino functionality (3IP Ar ). Accordingly, a series of palladium(II) complexes employing this new ligand have been synthesized and utilized in the intermolecular hydroamination of 3-methyl-1,2-butadiene (1,1-dimethylallene) and 2,3-dimethyl-1,3-butadiene...
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