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Fluorine-modified Cu/Zn/Al catalyst was prepared by calcination of the fluorine-containing Cu/Zn/Al hydrotalcite-like precursor and tested for CO 2 hydrogenation to methanol. The introduction of fluorine into Cu/Zn/Al catalyst led to lower CO 2 conversion mainly due to the decrease of the exposed copper surface area. However, the turnover frequency increased remarkably owing to the...
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