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The investigation of intermolecular free volumes in resorcinol was conducted under high pressure, hydraulic pressure and gas (argon or nitrogen) atmosphere. The sizes of free volumes were estimated basing on the mean lifetime of ortho-positronium (o-Ps). In the first case, a monotonous change of lifetime and intensity was observed for the o-Ps component while the range of pressure was 0-477 MPa. On...
In this work we employed positron lifetime spectroscopy for investigation of the thermal development of free volumes in H⁺ Nafion membrane over a broad range of temperatures from -150 to 150°C. Positron lifetime studies were combined with differential scanning calorimetry. Size distribution of free volumes was determined from ortho-positronium contribution to positron lifetime spectra. Our investigations...
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