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Reactions of nickelocene, NiCp2, with organolithium compounds RLi (R = -C_CPh; -CPh=CPh2; -CPh3, -CPh2SiMe3), where R does not contain _- and _-hydrogen atoms, have been studied. It was found that {CpNiR}, formed in the first step of the reaction, underwent coupling with the formation of {(NiCp)2} and R-R. As organolithium substrates are readily available, and yield of coupling products was high (from...
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