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Correlated single‐atom catalysts (c‐SACs) with tailored intersite metal–metal interactions are superior to conventional catalysts with isolated metal sites. However, precise quantification of the single‐atomic interdistance (SAD) in c‐SACs is not yet achieved, which is essential for a crucial understanding and remarkable improvement of the correlated metal‐site‐governed catalytic reaction kinetics...
Single‐Atom Catalysts
In article number 2310699, Bowen Jiang, Cheng Chen, Zongkui Kou, and co‐workers report the precise manipulation of single‐atomic Ru interdistances via a planar organometallic molecular design. Assembling the Ru interdistance to a rational level produces long‐range interaction for electrocatalysis, whereas the unassembled ones are “on tiptoes” outside electrocatalysis.
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