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The organoplatinum complex containing ortho-metalated (S)-[1-(dimethylamino)ethyl]naphthalene as the chiral auxiliary has been used to promote the asymmetric cycloaddition reactions between 3,4-dimethyl-1-phenyl phosphole and (E)-1-phenyl-3-pyridin-2-yl-2-propenone or (E)-1-methyl-3-pyridin-2- yl-2-propenoate in high selectivity under mild condition. However, the corresponding palladium complex didn't...
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