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The hydrogen out-of-plane bending (HOOP) vibrations were studied in the difference Fourier transform infrared spectra of lumirhodopsin and metarhodopsin I by use of a series of specifically deuterated retinal derivatives of bovine rod outer segments. The 947 cm -1 band of lumirhodopsin and the 950 cm -1 band of metarhodopsin I were assigned to the mode composed of both 11-HOOP...
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