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Counterions of manganese(III) porphyrin complexes influence diastereoselectivity in cis-stilbene epoxidation and product distribution in cyclohexene epoxidation markedly. In the epoxidation of cis-stilbene by iodosylbenzene carried out in a solvent mixture of CH 3 CN and CH 2 Cl 2 , trans-stilbene oxide is the major product in the reaction of manganese complexes bearing a ligating...
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