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The structural properties of the La x Sm 1−x FeO 3 trimetallic orthoferrites are described on the basis of a Rietveld analysis of X-ray diffraction pattern. Ultrafine powders of these oxides are prepared by the thermal decomposition at low temperatures of the corresponding hexacyanocomplexes. Single-phase compounds are obtained. Their structural parameters can be tuned by properly...
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