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Electrospray ionization, followed by gas-phase hydrogen/deuterium exchange and Fourier transform ion cyclotron resonance mass analysis provide a means for correlating the gas-phase and solution-phase conformations of a protein. Multiple gas-phase conformations (based on different rate and extent of deuterium incorporation) are found for each of the 6+, 7+, and 8+ charge states of the N-terminal domain...
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