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By a metastable rocksalt ZnO interfacial structure and a resulting rocksalt-to-wurtzite structure transition in ZnO buffer layer, polarity control of Zn-polar ZnO films was realized on rocksalt MgO (111) template by plasma-assisted molecular beam epitaxy. The metastable rocksalt ZnO and the phase transition from octahedrally bonded rocksalt to tetrahedrally bonded wurtzite structure during the growth...
Metastable structures of MgO overlayer on type-III oxide surfaces were achieved by molecular beam epitaxy. Periodic out-of-plane dipole moment of substrates was revealed to play a dominant role in the formation of metastable oxide structures. Under near-equilibrium epitaxial conditions, this dipole moment was found to drive the over-grown MgO to inherit the out-of-plane substrate lattice, resulting...
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