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Substitutions of Ti and Cu in ZrO 2 .MgO (Z), cause transformation from monoclinic (m) to cubic (c) and tetragonal (t). According to the vacancy model and solid solution formation models, neither CuO nor TiO 2 cause zirconia stabilization, which derives from other phenomena. Data analysis by TMA using the CRH (constant rate of heating) method shows a solid state reaction of ZrO ...
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