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Site-specific deposition of metal nanoparticles (NPs) on metal oxide surfaces is challenging but of particular importance for the development of catalytic materials with improved or new performance. We report here that Ru NPs can be directed to the rutile/anatase junction of P25 TiO2 via a facile wetness impregnation–chemical reduction method at room temperature. In the partial hydrogenation of benzene...
The B-doped ZrO 2 (B-ZrO 2 ) samples with different B/Zr ratios were synthesized using zirconium oxychloride and boric acid as the precursors. Their crystallographic phase retained as tetragonal ZrO 2 after the doping of B; however, the amount of the Lewis acid sites increased from 46.1μmol NH3 g −1 on ZrO 2 to 100.6μmol NH3 g −1 on B-ZrO...
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