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The mixed-valence compound [Cu I (dmp) 2 ][Cu II (hfac) 3 ] with dmp=2,9-dimethyl-1,10-phenanthroline and hfac - =hexafluoroacetylacetonate has been synthesized and structurally characterized by X-ray crystallography. The MV interaction has been examined by emission spectroscopy. The phosphorescence of [Cu I (dmp) 2 ] + is completely...
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