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A summary of our recent works on fulleropyrrolidines and fullerotriazolines covalently attached to the strong electron-donor tetrathiafulvalene (TTF) is presented. Absorption of light in C 60 -based TTF-containing dyads leads to the formation of the fullerene excited singlet state, which undergoes an intramolecular electron transfer to give the charge-separated (CS) state. A further stabilization...
The concept of linking fullerenes to a number of interesting electro- or photoactive species and their subsequent study of intramolecular transfer dynamics between the two moieties is described as a function of excited state energy of the antenna molecule, donor-acceptor distance, and solvent polarity.
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