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The new metastable binary europium silicide EuSi 6 and its ternary derivative EuSi 6−x Ga x (x=0–0.60) were prepared by applying a pressure of 8 GPa and a temperature of 1520 K. Single crystal and powder diffraction data refinements reveal that the compounds crystallize orthorhombic (space group Cmcm, a=4.4489(3) Å, b=10.2229(7) Å, c=11.6160(5) Å for EuSi 6 ) and are...
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