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Two series of copper(I) complexes with diethoxyphosphoryl‐substituted 1,10‐phenanthroline ligands were synthesized and characterized in the solid state and in solution. The first comprised mixed‐ligand CuI complexes with phenanthroline and triphenylphosphine. The second series includes bis‐chelates with two phenanthroline ligands. According to the X‐ray data for the six complexes, the ditopic phenanthroline...
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