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This work deals with the synthesis and characterization of two homogeneous and three heterogeneous iron(III) catalysts, which were evaluated in the oxidation of cyclohexane and cyclohexene, using H2O2 as oxidant. The homogeneous catalyst [Fe2(BPA)2(μ-OCH3)2(Cl)2], (1), where BPA is the deprotonated form of N-(2-hydroxybenzyl)-N-(pyridin-2-ylmethyl) amine, is a dinuclear iron(III) compound, as determined...
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