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γ-B28 is a recently established high-pressure phase of boron. Its structure consists of icosa-hedral B12 clusters and B2 dumbbells in a NaCl-type arrangement (B2)δ+(B12)δ− and displays a significant charge transfer δ ∼ 0.5–0.6. The discovery of this phase proved to be essential for the understanding and construction of the phase diagram of boron. It was first experimentally obtained as a pure boron...
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